I don't often post as a quick search almost always finds what I need & I never seem to have anythng usefull to say thats not already been said

About 4 months ago I had a front heater matrix go, I replaced it & follow the funnel bleed method to refill the coolant it was a pain to do but all has been fine until yesterday (done about 3000 miles). I had the front heater on full & the blower on for about 15mins, I started to smell the dreaded foul water smell. Checked the front matrix & no problem. However there was a pool of hot water midway under the van (drivers side). Looks like it was coming out of an overflow pipe for the rear heater. Any thoughts on why this might be?
When I last checked water (about 2 months ago, yes I know

Any thoughts would be much appreciated.
Cheers
Stuart