Well its a standard 40 Amp relay.
Exactly what it controls is anyone's guess
But given that one connection is to the L/B via fuse it could be your charging relay, in which case one of the other THREE connections will go to the S/B via fuse. The other two connections, one is most likely to go to earth/chassis and the other to 12 volts via the ignition switch, so that when your running the relay operates and the two batteries are connected in parallel to be charged from the alternator.
Looking closely at the picture I think I can actually just make out 4 wires going to the relay, in which case the spare one is not needed but the one at the back nearest the bulkhead is difficult to make out so it might have come from there.
When does the L/B fuse blow ? Is it when you start the engine up ? Is it when you turn on devices that run from the L/B ? What size fuse is it to the L/B ?