Here's some of my understanding - I hope it helps and doesn't confuse things...
banjoboy1 wrote:What would be the consequences if any of overfilling?
In a healthy system.... simply put, overfilling with coolant means the header tank would have less air in it. There being slightly more coolant to expand when hot, it would squash the air that is in the header tank a little more and you'd reach the 1.1 bar pressure of the header tank cap a bit sooner, which, if operating correctly, would then vent off a little air to ensure the overall pressure stays at or below 1.1 bar. In the extreme, the coolant may thermally expand
enough to leave "no" air in the header tank, at which point you will blow off excess coolant via the header tank cap pressure relief cap and overflow hose, and end up with a soggy mess under the bonnet, not in itself a problem. On cooling, the coolant will contract, and the pressure of however much air is in the header tank will drop, if dropping to -1psi, then the header tank cap will suck in a little more air. In short, "it will find it's own balance", but overfilling is not necessarily a bad thing in itself. That said, you may see something like 10-13psi in a "normal" system (though there are many factors) and overfilling will mean the system is "more likely" to see maximum pressure around 16psi (or 1.1 bar), at which point you may be "stressing" hoses more than you might otherwise. It's complicated again if you've just bled the system and are sealing an unpressurised, fully expanded system by putting the header tank on when hot, so you need a couple of heat/cool cycles for it to "settle". Also, it is possible that some other part of the system is going to allow air "in" before the negative pressure valve of the header tank cap - it is generally thought that small amounts of air can get sucked in variously around thermostat seal, waterpump seal, hose stubs, etc..., "instead" of the header tank cap - in these cases, then you may incrementally build up an air bubble somewhere in the system other than in the header tank cap, which if not removed by turbulence during engine operation, would be "a bad thing". There is no need to overfill, other than perhaps straight after bleeding when you're already at temperature, with thermally expanded coolant, and know that there may be the odd little bit of air to come out under driving conditions, overfilling in that case to ensure that when the level drops due to air expulsion and subsequent cooling/contraction, it doesn't drop out of the header tank completely.
banjoboy1 wrote:What temp is boiling in a pressurised system?
Temperature of what, and measured where? What %age mix of antifreeze to water? The hottest part of the cooling system is going to be the waterways around the combustion chambers of the block and exhaust ports of the head. The coolant should be able to tolerate this maximum heat, which you will probably find difficult to measure. "Localised boiling" around these parts is what is going to cause the issue, as steam will expand violently with respect to the coolant from which it comes. If you're measuring metal temperature some distance away from here through metal thickness(es), you're measuring something slightly different, so the temperature of coolant that may have already reached boiling point is not necessarily going to be consistent with the figure on your temperature read-out, though in practice I'm sure it's good enough to make some judgement - I'm just taking my explanation a little further. Furthermore, if you've got an air lock or boiling in progress, then coolant will not be circulating and the cylinder head temperature will rise significantly higher/faster than the point at which you're measuring the temperature either of coolant or of metal surface temperature, until you lose coolant, the heat reaches the temp sensor, etc... and then stop. This is more or less how the damage can occur. Some parts of the system will always be hotter than others - obviously the rad and heater matrices remove heat for example. If you've got airflow under the van and around the engine, you've got heat exchange going on in the rad/matrices and also a bit more cooling of the metal bulk of the engine itself, versus being stationary where the hotter parts of the engine are slowly soaking the rest in heat which is not being removed very much, etc... If your engine is off and you haven't boiled over yet, you're not going to - as you're not introducing any more heat, even if your temperature readout appears to be rising due to heat soak. If you leave the engine running to keep coolant circulating, then the thermostat will open and rad fan(s) will come on to ensure that the temperature of the coolant does not keep increasing. A long way round to say that a heat rise when stationary is not uncommon, the figure you're seeing and the alarm threshold which you have set, may not be unusual themselves...
When you rose to 110, was the engine running to circulate coolant? Or was it the "scavenger fan" in the engine bay running rather than the radiator fan(s)? If the rad fans were to continually cool the same coolant that is in the rad without the engine running and hence the water pump circulating it and replacing it with hot, then that's not going to reduce engine block/head temperature much. If the scavenger fan is blowing air through the engine bay but the coolant itself is not being actively cooled, then again, temperature won't come down particularly fast.
Others with the same temp gauge installed in the same position, may be able to share their experience regarding specific temperatures, etc... that may be more what you're after...