Why More Antifreeze Isn't Better
Water, with the proper anticorrosion additives, would make an adequate cooling medium for automotive engines. But it freezes, and boils over. Ethylene glycol, an alcohol, is added to extend the boiling and freezing points of the coolant. Why not run pure glycol, and get better freezing/boil-over protection? As you can see from the chart, pure ethylene glycol will freeze at essentially the same temperature as water. At concentrations higher then 70 percent or so, freeze protection is not very good. Also, ethylene glycol doesn't carry as much heat from the engine to the radiator as an equivalent amount of water, which can result in overheating. Stick with concentrations of 50 percent to 60 percent water/antifreeze.

Basic chemistry tells us that pure water is the best coolant, period. The specific heat of water is 1.0. This is the common chemistry benchmark that says that it takes 1 BTU to raise 1 pound of water 1° F and is assigned the 1.0 specific heat number. A 50/50 mix of ethylene glycol (the green stuff) has a tested specific heat number of 0.5 and of propylene glycol of 0.3.
What this means is that it take twice the amount, in the case of the Green/Blue stuff (and over three times for the Red stuff) of BTUs to raise the same amount of water 1 degree!! This means that pure water will remove double the amount of heat and carry that heat away from the source per unit volume. Now, do the arithmetic and you will find out that the more pure water...the more heat gets taken away! Do not confuse this with the boiling point of the coolant. Pure water will boil at a lower temperature than that of a mix of water and antifreeze, as well as freeze at a higher point.