My two penneth worth would be to say that the biggest design factors influencing convection would I reckon be:
* the surface area to volume ratio of the hot body (rad+contents - in practical terms how many thin pipes and thin cooling fins connected to them)
* the ease with which the rising hot air can escape / be drawn away by the conveciton process (in practical terms how freely air can flow through the pipe/fin matrix, and how easily the rising air can escape so as enable rapid replacement with cold air from e.g. underneath the radiator.
The best chance of something approaching the effect of a chimney might be hot air hitting the angled bonnet underside and moving up and back to exit the gap at the back of the bonnet. This would encourage cool air to be drawn in through the radiator grille to complement air being pulled up from beneath. But all that is just a guess and would need checking by taking readings, making observations etc.
I wonder what the baffle in Kirstys pic is about. Maybe there to protect the engine bay from stuff thrown up by the road? It might also be a bit beneficial when convection only is at work by reducing pre-warming of cool air through black body radiation from the main engine mass as well as encouraging airmass to 'chimney up' through the radiator opening. But I think that's really starting to push the bounds of credibility where the thoughts of the designers are concerned
Some experiments with smoke sources, to trace path taken by airmass, could be rather good fun.